Solution−Liquid−Solid Growth of Ternary Cu−In−Se Semiconductor Nanowires from Multiple- and Single-Source Precursors

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Abstract
Ternary CuInSe(2) nanowires were synthesized for the first time by the solution-liquid-solid (SLS) mechanism. Here, both metal-organic multiple- and single-source molecular precursors were thermally decomposed in the presence of molten metal nanoparticles and coordinating ligands. The nature of the precursor-multiple- compared to single-source (wherein Cu-Se-In bonds are effectively preformed)-as well as the choice of coordinating ligands, reaction temperature, and reactant order-of-addition strongly affected the morphology and composition of the reaction product obtained. Crystalline, straight, and nearly stoichiometric CuInSe(2) nanowires were most readily achieved using the single-source precursor; however, careful tuning of reaction conditions could also be used to obtain high-quality nanowires from multiple-source precursor systems. The CuInSe(2) nanowires are strong light absorbers from the near-infrared through the visible and ultraviolet spectral regions and, thereby, comprise new soluble and processable "building blocks" for applications in solar-light harvesting.