Photoelectron spectrum of Ca between 11 and 28 eV

Abstract
We present a calculation of the photon energy dependence of the photoelectron spectrum of Ca from 11 to 28 eV, roughly the region between the 4p threshold and the lowest resonance due to 3p3d excitations. Because of the occurrence of a "Cooper minimum" for 4sεp excitation close to threshold, which is not reproduced for the satellites, we predict that at low photon energy the 3d and particularly the 4p satellite will be stronger than the main 4s line.

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