Monohapto co-ordination of poly(tert-butylpyrazolyl)borate ligands in nickel and palladium complexes
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 17,p. 2651-2652
- https://doi.org/10.1039/dt9920002651
Abstract
Several four-co-ordinate nickel and palladium aryl and aroyl complexes containing the bulky bis- or tris(3-tert-butylpyrazolyl)borate ligands have been prepared, in which the poly(pyrazolyl)borate group adopts monohapto co-ordination, both in solution and in the solid state.Keywords
This publication has 33 references indexed in Scilit:
- Ring migration reactions of (C5Me5)Rh(PMe3)H2. Evidence for .eta.3 slippage and metal-to-ring hydride migrationOrganometallics, 1991
- Computational evidence for a nonplanar .eta.3-cyclopentadienyl ligand in dicarbonylbis(cyclopentadienyl)chromium and the pathway for the .eta.5.tautm..eta.3 ring interchangeOrganometallics, 1991
- Synthesis and X-ray crystal structure of the rhenium(VII)tert-butylimido compound, [Re(NBut)2(η1-C5H5)]2(µ-C5H4)(µ-O)Journal of the Chemical Society, Chemical Communications, 1991
- A molecular orbital study of conformational preferences of the cyclopentadienyl ligand in titanium(IV) and titanium(III) complexesOrganometallics, 1989
- Reversible formation of .eta.1 -and .eta.0-cyclopentadienyl complexes by treatment of [M(C6H4N:NC6H4R)(.eta.5-C5H5)] (M = Pd, Pt) with tertiary phosphinesOrganometallics, 1987
- Novel polypyrazolylborate ligands: coordination control through 3-substituents of the pyrazole ringInorganic Chemistry, 1987
- Ring-slippage chemistry of transition metal cyclopentadienyl and indenyl complexesChemical Reviews, 1987
- Synthetic, structural, and theoretical studies of .eta.2-acyl complexes of molybdenumJournal of the American Chemical Society, 1986
- The Coordination Chemistry of Pyrazole‐Derived LigandsPublished by Wiley ,1986
- Mono-η-cycloheptatrienyltitanium chemistry: synthesis, molecular and electronic structures, and reactivity of the complexes [Ti(η-C7H7)L2X](L = tertiary phosphine, O- or N-donor ligand; X = Cl or alkyl)J. Chem. Soc., Dalton Trans., 1985