η-Cyclopentadienyl molybdenum imido compounds; halo, alkene, alkyne, allyl and tertiary phosphine derivatives
- 1 January 1992
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 256-259
- https://doi.org/10.1039/c39920000256
Abstract
The new imido compounds [M(η-C5H4R)Cl2(NR′)]*(M = Mo, R = H, R′= But, Prn or Ph; M = Mo, R = Me, R′= But or Ph; M = W, R = H, R′= But), [Mo (η-C5H4R)Cl(L)(NR′)](R = H, R′= But, L =η-C2H4, or η-C2Me2; R = Me, R′= But, L = C2H4*; R = H, R′= Ph, L =η-C2Me2), [{Mo(η-C5H4R)(η-C2H4)(NBut)}2Hg]*(R = H, Me), [Mo (NBut)Cl2(PMe3)3], [Mo(η-C5H5)Cl3(NBut)] and the π-allyl complex [Mo(η-C5H4Me)(η-C3H5)(NBut)] are synthesised; *indicates that the crystal structure has been determined.Keywords
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