Control of hydrogen bonding in the design of new diol lattice inclusion compounds
- 1 February 1993
- journal article
- research article
- Published by Taylor & Francis in Supramolecular Chemistry
- Vol. 1 (2) , 171-178
- https://doi.org/10.1080/10610279308040663
Abstract
In order to be able to predict and then synthesize new lattice inclusion compounds with the helical tubuland diol host structure, the hydrogen bonding modes of a range of bicyclic and tricyclic diols have been studied using X-ray crystallography. Several distinct types of lattice structure have been recognized. Steric factors play a major role in determining which of these is produced in a given case. Establishment of a series of structural rules provides a window of opportunity for duplication of the helical tubuland host lattice by deliberate design and synthesis. New inclusion compounds resulting from this approach are presented.Keywords
This publication has 10 references indexed in Scilit:
- Crystal structures of helical tubulate inclusion compounds formed by 2,6-dimethylbicyclo[3.3.1]nonane-exo-2,exo-6-diolJournal of the Chemical Society, Perkin Transactions 2, 1992
- Generation of possible crystal structures from molecular structure for low-polarity organic compoundsJournal of the American Chemical Society, 1991
- 2,6-Dimethylbicyclo(3.3.1)nona-3,7-diene-endo-2,endo-6-diol, an Alicyclic Diol Whose Crystal-Structure Involves Two Types of Hydrogen-Bonded ColumnsAustralian Journal of Chemistry, 1991
- Syntheses and crystal structures of seven alicyclic diols which crystallise with layer structures instead of the helical tubuland inclusion latticeJournal of the Chemical Society, Perkin Transactions 2, 1990
- Preparation and crystal structure of a twin twist-boat bicyclo[3.3.1]nonane monohydrateJournal of the Chemical Society, Perkin Transactions 1, 1989
- The significance of molecular type, shape and complementarity in clathrate inclusionPublished by Springer Nature ,1988
- Molecular determinants of a new family of helical tubuland host diolsJournal of Inclusion Phenomena, 1987
- Modification of tube size and shape in a helical tubuland inclusion lattice formed by a new family of diol hosts: syntheses and crystal structuresJournal of the Chemical Society, Perkin Transactions 2, 1986
- A proposal for the classification and nomenclature of host-guest-type compoundsJournal of Inclusion Phenomena, 1983
- Different crystal structures of inclusion complexes formed by syn-2,syn-7-dihydroxy-2,7-dimethyltricyclo[4.3.1.13,8]undecane with ethyl acetate and benzeneJournal of the Chemical Society, Chemical Communications, 1983