New soluble functional polymers by free‐radical copolymerization of methacrylates and bipyridine ruthenium complexes
- 5 November 2003
- journal article
- research article
- Published by Wiley in Journal of Polymer Science Part A: Polymer Chemistry
- Vol. 41 (24) , 3954-3964
- https://doi.org/10.1002/pola.10959
Abstract
The luminescent complex [4‐(3‐hydroxypropyl)‐4′‐methyl‐2,2′‐bipyridine]‐bis(2,2′‐bipyridine)‐ruthenium(II)‐bis(hexafluoroantimonate) and its methacrylate derivative were successfully synthesized and fully characterized by two‐dimensional 1H and 13C{1H} NMR techniques [correlation spectroscopy (COSY) and heteronuclear multiple‐quantum coherence experiment (HMQC)], as well as matrix‐assisted laser desorption ionization time‐of‐flight mass spectrometry. The respective labeled methyl methacrylate‐ruthenium(polypyridyl) copolymers were obtained by free‐radical copolymerization with methyl methacrylate and were characterized utilizing NMR, IR, and UV–visible spectroscopy and gel permeation chromatography. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3954–3964, 2003Keywords
This publication has 25 references indexed in Scilit:
- Electroluminescent device with reversible switching between red and green emissionNature, 2003
- Luminescent polymeric ruthenium complexes with polystyrene-b-poly(methyl methacrylate) macroligands: The sequential activation of initiator sites for blocks generated by parallel polymerization mechanismsJournal of Polymer Science Part A: Polymer Chemistry, 2002
- Metallo-Supramolecular Graft Copolymers: A Novel Approach Toward Polymer-Analogous ReactionsMacromolecular Rapid Communications, 2002
- Effect of Medium Environment on the Propagating Step in Free-Radical PolymerizationThe Journal of Physical Chemistry B, 2002
- Polystyrene with Pendant Mixed Functional Ruthenium(II)-Terpyridine ComplexesMacromolecular Rapid Communications, 2002
- Single layer light-emitting devices with high efficiency and long lifetime based on tris(2,2′ bipyridyl) ruthenium(II) hexafluorophosphateJournal of Applied Physics, 2001
- Stereocontrol during the free‐radical polymerization of methacrylates with Lewis acidsJournal of Polymer Science Part A: Polymer Chemistry, 2001
- Stereocontrol in the free-radical polymerization of methacrylates with fluoroalcoholsJournal of Polymer Science Part A: Polymer Chemistry, 2000
- Poly(methyl methacrylates) with Ruthenium Tris(bipyridine) Cores via NiBr2(PR3)2-Catalyzed Atom Transfer Radical Polymerization (ATRP)Macromolecules, 2000
- The electroluminescence of organic materialsJournal of Materials Chemistry, 2000