Synthesis of β-Amino Acid Derivatives by Nickel(0)-mediated Sequential Addition of Carbon Dioxide and Dibenzoyldiazene onto Unsaturated Hydrocarbons
- 24 February 2007
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 36 (3) , 476-477
- https://doi.org/10.1246/cl.2007.476
Abstract
A stoichiometric amount of nickel(0) complex mediated the aminative carboxylation of unsaturated hydrocarbons through oxidative cyclization with carbon dioxide followed by insertion of dibenzoyldiazene into the carbon–nickel bond, giving β-amino acid derivatives.Keywords
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