Thermodynamic calculations for liquid alloys with an application to sodium-caesium
Open Access
- 1 August 1980
- journal article
- Published by IOP Publishing in Journal of Physics F: Metal Physics
- Vol. 10 (8) , 1681-1692
- https://doi.org/10.1088/0305-4608/10/8/008
Abstract
A semi-empirical model is presented for the analysis in liquid alloys of the long wavelength limit of the structure factor, the free energy of mixing and the electrochemical potential. The formalism is partly based on statistical mechanics assuming a concentration-dependent hard-sphere behaviour of liquid alloys. Although being conceptually quite different, the description incorporates the Flory-Huggins model as a first approximation.Keywords
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