Superconductivity Near 50 K in a Bi-La-Ca-Cu-O System

Abstract
A new oxide superconductor has been found in the Bi-La-Ca-Cu-O system. The maximum onset temperature and zero resistance temperature were 52 K and 21 K, respectively, obtained for a nominal composition of Bi2La0.5Ca3.5Cu3O x ceramics sintered at 830°C for 110 h in air. The powder X-ray diffraction patterns of this ceramic were well indexed by a tetragonal symmetry with a=0.54 nm and c=2.98 nm, which is similar to that of Bi2Sr2CaCu2O x ceramics.

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