Reactions d'Heterocycles Oxygenes avec Les Trialcoylsilyl-, Germyl- et Stannylphosphines: I: Dialcoylphosphinoalcoxy-Germanes, -Silanes et -Stannanes
- 1 January 1971
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 1 (3) , 163-169
- https://doi.org/10.1080/00945717108057566
Abstract
The reactions of trialkylmetalphosphines R3MPR'2 (M = Si, Ge, Sn) with the cyclic ethers lead, by cleavage and insertion on the metal-phosphorus bond, to dialkylphosphinoalcoxysilanes, germanes and stannanes. The silylphosphines are more reactive than isolog germyl- and stannylphosphines in this type of reaction, and only silylphosphines cleave the tetrahydrofuranKeywords
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