Indium-Catalyzed Addition of Active Methylene Compounds to 1-Alkynes
- 1 October 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (43) , 13002-13003
- https://doi.org/10.1021/ja038006m
Abstract
An active methylene compound adds to a 1-alkyne in high to quantitative yield upon heating in the presence of 0.05−5 mol % of In(OTf)3 to give an α-alkenylated carbonyl compound.Keywords
This publication has 3 references indexed in Scilit:
- Catalytic Radical Addition of Carbonyl Compounds to Alkenes by Mn(II)/Co(II)/O2 SystemThe Journal of Organic Chemistry, 2002
- Addition of Azaenolates to Simple, Unactivated OlefinsAngewandte Chemie International Edition in English, 1997
- The mechanism of the zirconium-catalyzed carbomagnesiation reaction. Efficient and selective catalytic carbomagnesiation with higher alkyls of magnesiumJournal of the American Chemical Society, 1992