Catalytic Radical Addition of Carbonyl Compounds to Alkenes by Mn(II)/Co(II)/O2 System
- 12 January 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 67 (3) , 970-973
- https://doi.org/10.1021/jo0162282
Abstract
The radical addition of enolizable carbonyl compounds such as malonates and malononitrile to alkenes was successfully achieved through a catalytic process using the Mn(II)/Co(II)/O2 system to afford the corresponding adducts in fair to good yields. Dimethyl malonate added to 1,5-cyclooctadiene to produce a fused bicycle compound.Keywords
This publication has 18 references indexed in Scilit:
- Catalytic radical addition of ketones to alkenes by a metal–dioxygen redox systemChemical Communications, 2000
- Two-Component Gelators and Nucleating Agents for Polypropylene Based upon Supramolecular AssemblyMacromolecules, 1998
- Manganese(III)-Mediated Radical Additions of Dimethyl Malonate to Olefins. The Chemoselective Synthesis of Diesters and LactonesSynlett, 1996
- Zur oxidativen Dimerisierung von CH‐SäurenEuropean Journal of Inorganic Chemistry, 1994
- The Tin Hydride Reductive Decyanation of Geminal DinitrilesSynlett, 1991
- Palladium-catalysed 1,4-arylation/alkylation of buta-1,3-diene with halogenoarenes and stabilised anionsJournal of the Chemical Society, Perkin Transactions 1, 1990
- The Design and Application of Free Radical Chain Reactions in Organic Synthesis. Part 2Synthesis, 1988
- Highly stereo- and regioselective alkylation of alkylidenemalonates. Application to the synthesis of (.+-.)-canadensolideThe Journal of Organic Chemistry, 1986
- Metal Oxide-Initiated Alkylation of Compounds Containing Activated Methene Groups with Terminal AlkenesSynthesis, 1977
- Radical Addition of Ketones to Alkenes Initiated by Transition Metal Oxides1Synthesis, 1976