Photoionization and photodissociation of nitric oxide in the range 9–35 eV
- 22 February 1995
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 102 (8) , 3064-3076
- https://doi.org/10.1063/1.468616
Abstract
Photoionization and photodissociation of NO has been studied using 9–35 eV synchrotron light and detection of fluorescence as well as of mass selected NO+, N+, O+, and O− ions. Rydberg series converging to all known states in NO+ below 24 eV have been analyzed and classified and several of them are found to be predissociated by various NO+ states as well as by NO ion pair states. The complex structure in the 950–1200 Å excitation region is suggested to originate from interaction between a ‘‘new’’ NO valence state at T0=77 470 cm−1 and high vibrational levels of Rydberg series converging to the NO+ ground state.Keywords
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