The Optical Absorption Spectra of Ferrocene and Biferrocene Anions Produced in the γ-Ray Irradiation by the Matrix-protection Method
- 1 February 1981
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 54 (2) , 549-551
- https://doi.org/10.1246/bcsj.54.549
Abstract
The absorption spectra of the transient species produced through the one-electron reduction of ferrocene and biferrocene were determined by applying a radiation-chemical method in frozen glass matrices. The spectral shapes were assigned to ferrocene- and biferrocene-anionic species on the basis of the experimental results. In the biferrocene anion, the “intervalence transfer” band was observed at about 2050 nm.Keywords
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