Unusual Interlocking and Interpenetration Lead to Highly Porous and Robust Metal–Organic Frameworks
- 28 April 2009
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 48 (20) , 3637-3640
- https://doi.org/10.1002/anie.200806227
Abstract
Stop the breathing: As the organic bridging ligands become more elaborate and large, the resulting MOFs tend to experience significant framework distortion (i.e., breathing) upon solvent removal. Rigidification of MOFs that are built from elongated tetracarboxylate bridging ligands by unusual interlocking and interpenetration leads to highly porous and robust hybrid materials.Keywords
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