Chiral intermediates in thiamin catalysis. Stereochemical course of the decarboxylation step in the conversion of pyruvate to acetaldehyde
- 1 October 1987
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 109 (21) , 6368-6371
- https://doi.org/10.1021/ja00255a022
Abstract
No abstract availableThis publication has 5 references indexed in Scilit:
- Secondary .beta.-deuterium isotope effects in decarboxylation and elimination reactions of .alpha.-lactylthiamin: intrinsic isotope effects of pyruvate decarboxylaseJournal of the American Chemical Society, 1986
- Active site directed irreversible inactivation of brewers' yeast pyruvate decarboxylase by the conjugated substrate analog (E)-4-(4-chlorophenyl)-2-oxo-3-butenoic acid: development of a suicide substrateBiochemistry, 1983
- Thiamin-catalyzed decarboxylation of pyruvate. Synthesis and reactivity analysis of the central, elusive intermediate, .alpha.-lactylthiaminJournal of the American Chemical Society, 1981
- STUDIES ON HYDROXYETHYLTHIAMINE AND RELATED COMPOUNDSTHE JOURNAL OF VITAMINOLOGY, 1966
- On the Mechanism of Thiamine Action. IV.1 Evidence from Studies on Model SystemsJournal of the American Chemical Society, 1958