Asymmetric Intramolecular C−H Insertions of Aryldiazoacetates
- 21 April 2001
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 3 (10) , 1475-1477
- https://doi.org/10.1021/ol0157858
Abstract
The enantioselectivity of Rh2(S-DOSP)4 catalyzed C−H insertion of aryldiazoacetates is very dependent on the site of the C−H insertion. The highest enantioselectivity is obtained for insertion into methine C−H bonds.Keywords
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