Synthesis of some 3-O, 4-O, and 3,4-di-O-glycosyl-substituted methyl α-D-galactopyranosides
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 12,p. 2145-2151
- https://doi.org/10.1039/p19890002145
Abstract
Seven disaccharide and eight trisaccharide methyl glycosides required for n.m.r. and conformational studies have been synthesized. They are all derivatives of methyl α-D-galactopyranoside which has been 3-O-, 4-O-, or 3,4-di-O-glycosylated with either L-fuco- or D-gluco-pyranosyl groups. All anomeric forms were synthesized, either via thioglycosides and methyl triflate promotion or via glycosyl bromides and silver triflate promotion.This publication has 5 references indexed in Scilit:
- N.m.r. and conformational studies of the methyl glycosides of some 1,2- and 1,3-linked disaccharidesJournal of the Chemical Society, Perkin Transactions 1, 1988
- N.m.r. and conformational studies of some 1,4-linked disaccharidesJournal of the Chemical Society, Perkin Transactions 1, 1988
- N.m.r. and conformational studies on some 1,3-linked disaccharidesJournal of the Chemical Society, Perkin Transactions 1, 1988
- Nuclear magnetic resonance studies of 1,6-linked disaccharidesJournal of the Chemical Society, Perkin Transactions 1, 1985
- Regioselective alkylation and acylation of carbohydrates engaged in metal complexesCarbohydrate Research, 1984