Intramolecular Dehydrogenation of Alkyl Groups at Niobium Aryloxide Centers: Bonding and Reactivity of the Ensuing Niobacyclopropane Ring
- 15 October 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 15 (21) , 4443-4449
- https://doi.org/10.1021/om9604839
Abstract
No abstract availableKeywords
This publication has 36 references indexed in Scilit:
- Aryloxide ligand dependent reactivity of tantalum dihydride compounds with alkenesJournal of the Chemical Society, Chemical Communications, 1995
- Preparation and structure of a mixed niobium(I) isocyanide carbonyl complex with a bent C-N-C linkageInorganic Chemistry, 1991
- Competitive sp3 and sp2 carbon-hydrogen bond activation of phenols by W(PMe3)6 and W(PMe3)4(.eta.2-CH2PMe2)H: formation of four- and five-membered oxametallacyclesJournal of the American Chemical Society, 1990
- Synthesis and structural characterization of a Meerwein-Ponndorf-Verley/Oppenauer redox intermediate at a tantalum(V) centerOrganometallics, 1990
- Intramolecular activation of aliphatic and aromatic carbon-hydrogen bonds by tantalum(III) metal centers: synthesis and structure of the bis-metalated compounds Ta(OC6H3ButCMe2Ch2)2Cl and Ta(OC6H3PhC6H4)2(OAr-2,6-PH2) (OAr-2,6-Ph2 = 2,6-diphenylphenoxide)Organometallics, 1989
- Alkyne cyclizations at reduced tantalum centers: synthesis and molecular structure of (.eta.6-C6Me6)Ta(O-2,6-i-Pr2C6H3)2ClJournal of the American Chemical Society, 1987
- Synthetic and mechanistic aspects of intramolecular aliphatic carbon-hydrogen bond activation by titanium(IV) and zirconium(IV) metal centersJournal of the American Chemical Society, 1985
- Reactions of dinuclear niobium(III) and tantalum(III) compounds with alkyl isocyanides to give dinuclear products with dimerized isocyanidesJournal of the American Chemical Society, 1984
- Reactions of tert-butyl isocyanide with a binuclear niobium(III) compoundJournal of the American Chemical Society, 1983
- Structure and carbon-13 nuclear magnetic resonance spectrum of bis(cyclopentadienyl)ethyl(ethylene)niobiumJournal of the American Chemical Society, 1974