Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect
- 1 January 1992
- journal article
- Published by OOO Zhurnal "Mendeleevskie Soobshcheniya" in Mendeleev Communications
- Vol. 2 (4) , 137-139
- https://doi.org/10.1070/mc1992v002n04abeh000172
Abstract
Addition of alkali strongly accelerates the oxidation of cyciohexane by an iron tetramesitylporphyrin−NaOCl system, the selectivity of the reaction and the H−D kinetic isotope effect also being affected; possible mechanisms of OH − action are discussedKeywords
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- Aliphatic hydroxylation catalyzed by iron porphyrin complexesJournal of the American Chemical Society, 1983