Abstract
High‐quality amorphous silicon germanium (a‐SiGe:H) films are produced by a new ‘‘catalytic chemical vapor deposition (CTL CVD)’’ method. In the method, a SiH4, GeH4, and H2 gas mixture is decomposed without using any plasmas or photochemical excitation, but using only the thermal or the catalytic reaction with a heated tungsten catalyzer. Photoconductive properties of CTL CVD a‐SiGe:H are apparently not degraded as the Ge content increases. The photoconductivity and the photosensitivity for AM‐1 of 100 mW/cm2 are 105–104 (Ω cm)1 and 104, respectively, even for the sample of optical band gap of 1.40–1.45 eV.