Sodium Formaldehyde Sulphoxylate an Efficient Reagent For The Reduction of α-Haloketones
- 1 September 1987
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 17 (13) , 1587-1592
- https://doi.org/10.1080/00397918708057789
Abstract
Sodium formaldehyde sulphoxylate is shown to be an inexpensive, efficient reagent for the dehalogenation of phenacyl halides and other α-haloketones. Some possible mechanisms for the reduction are discussed.Keywords
This publication has 14 references indexed in Scilit:
- Debromination of phenacyl and benzylic bromides with tertiary stibine and the mechanistic considerationTetrahedron Letters, 1985
- A CONVENIENT METHOD FOR THE MILD REDUCTIVE DEBROMINATION OF α-BROMO KETONES AND OF vic-DIBROMOALKANES WITH STANNOUS CHLORIDE/DIISOBUTYLALUMINUM HYDRIDEChemistry Letters, 1984
- REDUCTION OF α-HALOCARBONYL COMPOUNDS WITH SODIUM HYDROGEN TELLURIDEChemistry Letters, 1983
- Dehalogenation of .alpha.-chloro and .alpha.-bromo ketones. Use of sodium O,O-diethyl phosphorotelluroateThe Journal of Organic Chemistry, 1982
- Reaction of α-Haloketones with Na2S2O4. A Convenient Dehalogenation ProcedureSynthetic Communications, 1982
- Addition von Aldehyden an aktivierte Doppelbindungen XXV1) Synthesen und Reaktionen von verzweigten Tricarbonyl‐VerbindungenEuropean Journal of Inorganic Chemistry, 1981
- Synthesis of d,l-muscone from cyclododecanoneJournal of the American Chemical Society, 1975
- Chromyl chloride in acetone. .alpha.-Chloro ketones and ketones directly from olefinsThe Journal of Organic Chemistry, 1973
- Cyclopentenones. Efficient synthesis of cis-jasomeThe Journal of Organic Chemistry, 1972
- Einige Verbesserungen von Nachweisen in der organischen TüpfelanalyseMicrochimica Acta, 1955