Fano profiles on multiphonon continua in electronic transitions of matrix-isolated NO
- 13 May 1991
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 66 (19) , 2499-2502
- https://doi.org/10.1103/physrevlett.66.2499
Abstract
Fano line shapes are reported in the excitation spectrum of the total fluorescence of NO trapped in Kr matrices. They result from the homogeneous configuration mixing of the sharp valence vibrational bands II(v’=12,15,18)-Π(v’ ’=0) with the broadened multiphonon Rydberg vibrational bands Π(v’=0,1,2)-Π(v’ ’=0). The main features of the spectrum are reproduced by a simulation.
Keywords
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