Neutral and Anionic Single-Bridged Binuclear Complexes of Gold(I) and Gold(III)
- 1 January 1981
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 11 (4) , 361-372
- https://doi.org/10.1080/00945718108055988
Abstract
The reaction between mononuclear gold complexes, containing a poorly coordinating anionic (OClO3 −) or neutral (tetrahydrothiophen or dimethylsulphide) ligand, and pseudohalide gold complexes leads to binuclear neutral or anionic derivatives of the types (C6F5)AuXAuPPh3, (C6F5)AuXAu(C6F5)2PPh3, (C6F5)3 AuXAuPPh3, (C6F5)3AuXAu(C6F5)2PPh3 or Ph3BzP[(C6F5) AuXAu(C6F5)] (X being SCN or N3). The (2:l) reaction of Q[(C6F5)AuX] or Q[(C6F5)3AuX] with AgClO4 leads also to anionic binuclear complexes of the types Q[(C6F5)AuXAu(C6F5)] or Q(C6F5)AuXAu (C6F5)3] (Q being Ph3BzP or μ-nitrido-bis(triphenylphosphorus); X being SCN or N3).Keywords
This publication has 10 references indexed in Scilit:
- Tris(pentafluorophenyl)(tetrahydrothiophen)gold(III)Inorganica Chimica Acta, 1980
- μ-Chloro-bis(triphenylphosphine)digold(I) perchlorate dichloromethane solvateActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1980
- Anionic perfluorophenyl complexes of gold(I) and gold(III)Inorganica Chimica Acta, 1979
- Unusual Cationic Single-Bridged Binuclear Complexes of Gold(I) and Gold(III)Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 1979
- Is Gold Chemistry a Topical Field of Study?Angewandte Chemie International Edition in English, 1976
- Preparation and properties of stable salts containing mono- or bis-(pentafluorophenyl)aurate(I) and mono-, tris-, or tetrakis-(pentafluorophenyl)aurate(III) ionsJournal of the Chemical Society, Chemical Communications, 1976
- Two New Ways for the Synthesis of Pentafluorophenyl-Gold(III) ComplexesSynthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 1973
- Antisymbiosis and the trans-effect in gold(I) thiocyanate complexesJournal of the Chemical Society, Chemical Communications, 1973
- Observations on the i.r. intensity criterion for the bonding mode in thiocyanate complexesJournal of Inorganic and Nuclear Chemistry, 1971
- Reaction of acetatotriphenylphosphinegold(I) with inorganic acids, alkyl halides, and bromineJ. Chem. Soc. A, 1969