REVIEW CHARACTERISTIC REACTIONS OF THE ALKOXY GROUPS OF THE ACID DIESTERS OF PHOSPHOROUS ACID
- 24 February 1987
- journal article
- review article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 29 (2) , 129-145
- https://doi.org/10.1080/03086648708080496
Abstract
This review presents the characteristic reactions of the alkoxy group of the acid diesters of phosphorous acid (RO)2 P(O)H: transesterification—with the phosphorus atom as the reaction center; alkylation—with the α-carbon atom as the reaction center; dealkylation—with the α-carbon atom as the reaction center. The possibilities of these reactions in the synthesis of end products with various structures and compositions are demonstrated. The perspectives for the practical application of these esters of phosphorous acid are discussed.Keywords
This publication has 14 references indexed in Scilit:
- ON THE SIDE REACTIONS ACCOMPANYING THE TRANS-ESTERIFICATION OF THE ACID DIESTERS OF PHOSPHOROUS ACIDPhosphorus and Sulfur and the Related Elements, 1984
- ON THE INTERACTION BETWEEN DIALKYL PHOSPHITES AND METAL SALTSPhosphorus and Sulfur and the Related Elements, 1983
- PHOSPHORUS AND METAL CONTAINING OLIGOMERSPhosphorus and Sulfur and the Related Elements, 1983
- A STUDY ON THE TRANSESTERIFICATION REACTION OF DIMETHYL AND DIETHYL PHOSPHITE WITH 1,3-DICHLOROPROPANOL-2Phosphorus and Sulfur and the Related Elements, 1982
- The mechanism of amine-catalyzed halohydrin formation from .alpha.-chloro ketones and phosphonate diestersThe Journal of Organic Chemistry, 1977
- Über die polykondensation von diäthylphosphit mit aliphastischen diolenDie Makromolekulare Chemie, 1973
- SYNTHESIS OF CYCLIC PHOSPHOROUS ACID ESTERS BY TRANSESTERIFICATIONCanadian Journal of Chemistry, 1959
- 176. Studies on phosphorylation. Part V. The reaction of tertiary bases with esters of phosphorous, phosphoric, and pyrophosphoric acids. A new method of selective debenzylationJournal of the Chemical Society, 1949
- 93. Esters containing phosphorus. Part IJournal of the Chemical Society, 1945
- Tautomerie der Dialkyl‐PhosphiteEuropean Journal of Inorganic Chemistry, 1912