[Au2Tl2(C6Cl5)4]·(CH3)2CO: A Luminescent Loosely Bound Butterfly Cluster with a Tl(I)−Tl(I) Interaction
- 1 May 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 124 (21) , 5942-5943
- https://doi.org/10.1021/ja017240e
Abstract
By reaction of NBu(4)[Au(C(6)Cl(5))(2)] with TlPF(6) in acetone the complex [Au(2)Tl(2)(C(6)Cl(5))(4)].(CH(3))(2)C=O is obtained, which shows a butterfly type arrangement of metals through short Au(I)-Tl(I) and Tl(I)-Tl(I) interactions. The last one is likely to be responsible for its luminescence behavior.Keywords
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