Efficient Polymer-Supported Sharpless Alkene Epoxidation Catalyst
Open Access
- 16 February 1998
- Vol. 3 (3) , 51-59
- https://doi.org/10.3390/30300051
Abstract
Homogeneous linear poly(tartrate ester) ligands provide high chemical yields and enantiomeric excesses in the epoxidation of trans-hex-2-en-1-ol using Ti(OPri)4-tert-butyl hydroperoxide. Branched poly(tartrate ester) can be use as heterogeneous ligands in the epoxidation of trans-hex-2-en-1-ol using Ti(OPri)4-tert-butyl hydroperoxide. Removal and recovery of the polymer catalyst is a simple filtration at the end of reactions.Keywords
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