Far-infrared properties of ab-plane oriented YBa2Cu3O7δ

Abstract
Polycrystalline samples of YBa2 Cu3 O7δ with a variety of surface treatments show differences in absolute reflectance and width of phonon lines. Samples that are not polished and are measured immediately after annealing have largely grains with the c axis normal to the surface. Such oriented samples show a gaplike depression of conductivity in the far infrared that sets in below the superconducting transition temperature but no true gap. Phonon lines at 195 cm1 and at 155 cm1 narrow in the superconducting state, in analogy with the effect of the electron-phonon interaction in Bardeen-Cooper-Schrieffer superconductors. In the normal state the background conductivity is Drudelike with a plasma frequency of 0.75 eV and a relaxation rate of 200 cm1. The extrapolated far-infrared conductivity agrees with the measured dc conductivity.