A Convenient Method for Production of Thionitrites and Disulfides Under Mild and Heterogeneous Condition
- 1 April 2000
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 30 (9) , 1593-1597
- https://doi.org/10.1080/00397910008087194
Abstract
Thiols can be readily converted to their corresponding thionitrite with a combination of inorganic acidic salts and sodium nitrite in dichloromethane at room temperature. Disulfides result from the homolytic cleavage of the sulfur-nitrogen bond of the unstable thionitrite and subsequent coupling of the resultant thiyl radicals.Keywords
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