Ligand Field Theory and the Absorption Spectra of MnCl2 and MnBr2
- 1 October 1959
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 31 (4) , 1050-1061
- https://doi.org/10.1063/1.1730502
Abstract
Optical absorption spectra of MnCl2 and MnBr2 at room temperature and 78°K are reported and discussed. Parameters of electrostatic interaction and internal field are derived. Koide and Pryce's formalism to compute transition probabilities is extended to 4T levels. Many properties of the absorption spectra are nicely explained by the ligand field theory.Keywords
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