Effect of the carbon acceptor concentration on the photoquenching and following enhancement of the photoacoustic signals of semi-insulating GaAs

The spectral and the time dependent piezoelectric photoacoustic (PPA) measurements under the continuous light illumination were carried out at 85 K to investigate nonradiative recombination processes involving EL2 defect levels in carbon concentration controlled and not intentionally doped semi-insulating (SI) GaAs. The decrease of the PPA signal due to the photoquenching effect of EL2 is observed for a short period of illumination in the photon energy region from 1.0 to 1.3 eV. Since almost all of the carbon acceptors are compensated by deep donor EL2 in SI GaAs, electron occupancy of EL2 level can be controlled by changing the carbon acceptor concentration. It is found that the photoquenching becomes drastic with increasing the carbon concentration. After fully photoquenching, the PPA signal increases again through a local minimum by the continuous light illumination and finally exceeds the initial value before illumination until the saturation level is reached. The deep donor level EL6 and its metastable state are proposed. EL6 level donates electrons to compensate a part of carbon acceptors after EL2${}^0$ to EL2^* transition is accomplished. The nonradiative recombination through this level generates the PPA signal. Since the PPA measurement can detect lower concentration of EL6 than that of EL2, the higher sensitivity of the PPA measurements than the optical absorption measurements is pointed out. The usefulness of the PPA technique for studying the nonradiative transition through deep levels in semiconductors is also suggested.