Determination of the deuterium quadrupole coupling constant in phosphine-d3 from studies in a nematic solvent
- 1 June 1974
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 60 (11) , 4223-4225
- https://doi.org/10.1063/1.1680891
Abstract
The phosphorus and deuterium Fourier transform NMR spectra of PD3 in a nematic solvent are reported. The experimentally determined value of the deuterium quadrupole coupling constant is 7.8±0.6 kHz in good agreement with the recent theoretical predictions of Rothenberg, Young, and Schaefer. The ordering parameter is unambiguously determined from the P–D splittings, thus enhancing the accuracy of the present results over previous measurements of this kind.Keywords
This publication has 7 references indexed in Scilit:
- The1H and31P N.M.R. spectra of phosphine in isotropic and nematic solventsMolecular Physics, 1974
- Fine structure in deuterium pure quadrupole resonanceJournal of Magnetic Resonance (1969), 1973
- NMR Determination of Some Deuterium Quadrupole Coupling Constants in Nematic SolutionsThe Journal of Chemical Physics, 1972
- Ground state self-consistent-field wave functions and molecular properties for the isoelectronic series SiH4, PH3, H2S, and HClJournal of the American Chemical Society, 1970
- NMR Determination of Deuterium Quadrupole Coupling Constants in Nematic SolutionsThe Journal of Chemical Physics, 1969
- One-to-Two Millimeter Wave Spectroscopy. V. Pand PPhysical Review B, 1954
- Note on an Approximation Treatment for Many-Electron SystemsPhysical Review B, 1934