Metal—olefin bonding. Preparations, spectra, and x-ray structures of chloro-1,6-bis (diphenylphosphino)-trans-hex-3-eneiridium(I), IrCl [(Ph2P(CH2)2CHCH(CH2)2PPh2], and chloro-1,6-bis(diphenylphosphino)-trans-hex-3-enedihydridoiridium(III), IrH2Cl(Ph2P(CH2)2CHCH(CH2)2PPh2]

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