A New Synthetic Method for α-Alkoxycarbonyl Iminium Salt and Its Reaction with Nucleophiles
- 18 February 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (10) , 3296-3297
- https://doi.org/10.1021/ja042330f
Abstract
An iminium salt was easily prepared using the oxidation of amino ketene silyl acetal with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone, and the subsequent nucleophilic addition to this iminium species proceeded efficiently to afford α-amino esters in good yields.Keywords
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