Tandem N-Alkylation−C-Allylation Reaction of α-Imino Esters with Organoaluminums and Allyltributyltin
- 11 March 2003
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (13) , 3720-3721
- https://doi.org/10.1021/ja029639o
Abstract
On treatment of various alpha-imino esters with organoaluminum reagents and allyltributyltin in the presence of benzoyl peroxide, the tandem reaction proceeded to give the N-alkylation-C-allylation products in good yields. The tandem N-alkyation-C-cyanation also proceeded using silyl or aluminum cyanide to give the aminonitrile in good yield.Keywords
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