Two-photon laser spectroscopy of thensandndautoionizing Rydberg series in xenon

Abstract
We have studied the odd-parity autoionizing levels in xenon by two-photon laser spectroscopy from the 6s[(3/2)]2 metastable level via various J=1,2 6p’ intermediate levels. Observed Rydberg series are ns’ [1/2]0,1, nd’ [(3/2)]1,2, and nd’ [(5/2)]2,3 with n ranging to, in some cases, n>80. This is the first observation of J≠1 odd-parity autoionization in xenon. These spectra are notable for the absence of the very intense, broad transitions to nd’ [(3/2)]1 which dominate photoabsorption from the J=0 ground state. We here present energy-level measurements for 140 levels. These extensive new data should be useful for further multichannel quantum-defect theory analysis of xenon.

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