Localization of Electrons in Intermetallic Phases Containing Aluminum
- 2 November 1994
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 33 (20) , 2069-2073
- https://doi.org/10.1002/anie.199420691
Abstract
Many forms of chemical bondingare exhibited by Al in intermetallic and Zintl phases. This is revealed by the calculation of the electron localization function for the series Al, CaAl2, SrAl2, BA14, CaAl2Si2, and Si. With this procedure it is possible to distinguish clearly between metallic, covalent multicenter, and homo‐ and hetero‐nuclear single bonding.Keywords
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