Analysis of the 5p6→5p5nl (J=1) Rydberg series in Ba2+

Abstract
A detailed analysis is made for the bound 5p6→5p5ns,nd levels observed in the photoabsorption of Ba2+. A multichannel quantum-defect theory approach, with ab initio calculations for some of the parameters, is used to describe periodic enhancements in intensity associated with interchannel mixing. Qualitative agreement between experiment and theory requires the inclusion of plasma-broadening effects to account for the apparent increase in strength of the higher n levels.