Abstract
An assumption of isospin symmetry permits the determination of sin(2α) from the experimental study of Bππ decays. Isospin, however, is merely an approximate symmetry; its breaking predicates a theoretical systematical error σαIB in the extraction of α. We focus on the impact of π0η,η mixing, as well as the manner in which it is amenable to empirical constraint, and determine that σαIB can potentially be controlled to O(1°).