ATTEMPTED PREPARATIONS OF PHOSPHORANES CONTAINING PERFLUOROPHENYL GROUPS
- 1 May 1982
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 13 (1) , 1-7
- https://doi.org/10.1080/03086648208078976
Abstract
The reaction of perfluorophenol with phosphorus pentachloride in the presence of triethylamine or γ-collidine yielded perfluoropentaphenoxyphosphorane, 5, along with perfluorotriphenylphosphate, 6, and perfluorodiphenyl ether, 7. Attempts to prepare penta(perfluorobenzyloxy)phosphorane, 12, by a number of methods failed. Similarly attempts to prepare perfluorothiophenylphosphorane, 19, always resulted in perfluorothiophenyl phosphite, 20, and perfluorodiphenyl disulfide, 21.Keywords
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