Enantioselective syntheses of (+)- and (–)-conduritol C from benzene via microbial oxidation and enzymatic asymmetrization
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1006-1007
- https://doi.org/10.1039/c39910001006
Abstract
The title compounds have been prepared by a route involving the elaboration of meso-cyclohexa-3,5-diene-1,2-diol 4, a product of microbial oxidation of benzene, to meso-diol 6 and asymmetrization of the latter by use of a lipase in organic media to the enantiometrically pure monoacetate 7.Keywords
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