New technique to dope GaAs crystals with the 111In→111Cd probe for perturbed-angular-correlation spectroscopy

Abstract
Perturbed‐angular‐correlation (PAC) spectroscopy is an important technique for measuring defect and dopant interactions in group IV and III‐V semiconductors. The probe of choice for most of the successful PAC experiments on semiconductors has been 111In→111Cd introduced by ion implantation. To expand the gamut of PAC experiments that can be performed on III‐V semiconductors, we have developed a simple closed‐tube, vapor‐phase‐epitaxy (VPE) technique to produce 111In‐doped GaAs single‐crystal epitaxial materials. PAC measurements on these crystals yielded nearly nonperturbed correlations that indicate that the 111In probe was incorporated substitutionally into the GaAs crystals. These correlations differ significantly from the previously reported weakly perturbed correlations that were measured on GaAs crystals implanted with 111In ions. An exploratory experiment using this VPE technique also showed that Sn can be incorporated along with 111In.