Die bildung von thiirenen
- 1 June 1978
- journal article
- other
- Published by Wiley in Journal of Heterocyclic Chemistry
- Vol. 15 (4) , 697-698
- https://doi.org/10.1002/jhet.5570150440
Abstract
Photochemical nitrogen elimination of 1,2,3‐thiadiazoles leads to primary fragments (1, X = S), which are able to cyclize to thiirenes (2, X = S). An exception is found for bicyclic systems like 4. These results, gained by isotope labelling experiments are related to the oxirene formation of α‐oxocarbenes.Keywords
This publication has 16 references indexed in Scilit:
- Thermische und photochemische Stickstoff‐CycloeliminierungenAngewandte Chemie, 1977
- Zur α‐Oxocarben‐Oxiren‐Isomerisierung: Photolyse von [1‐13C]‐2‐Diazo‐1‐phenyl‐1‐propanon und [2‐13C]‐1‐Diazo‐1‐phenyl‐2‐propanonAngewandte Chemie, 1977
- A methodology for the preparation and characterization of three-membered, potentially antiaromatic molecules. Preparation of matrix-isolated thiirene and selenireneJournal of the American Chemical Society, 1977
- Photolyse von 2-oxo-[2-13c]-1-diazocyclohexan. Ein beitrag zum oxiren-problemTetrahedron, 1977
- Mechanism of the Wolff rearrangement. 6. Ab initio molecular orbital calculations on the thermodynamic and kinetic stability of the oxirene moleculeJournal of the American Chemical Society, 1976
- Die Photolyse von 2‐Diazo‐[1‐ 13 C]naphthalin‐1(2 H )‐on und 1‐Diazo‐[1‐ 13 C]naphthalin‐2(1 H )‐on 1 Ein Beitrag zum Oxiren‐ProblemEuropean Journal of Inorganic Chemistry, 1975
- Die Wolff‐Umlagerung von α‐Diazocarbonyl‐VerbindungenAngewandte Chemie, 1975
- Zur Photolyse von 1.2.3‐Thiadiazolen, III1)European Journal of Organic Chemistry, 1973
- A MINDO/3 and NDDO study of antiaromatic three-membered rings and their valence tautomersJournal of the Chemical Society, Chemical Communications, 1973
- A non-empirical molecular orbital study of the Wolff rearrangementJournal of the Chemical Society, Perkin Transactions 2, 1973