Computation of Asymmetric Rotator Constants from Energy Moments. III. First‐Order Centrifugal Stretching Effects
- 1 November 1959
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 31 (5) , 1227-1230
- https://doi.org/10.1063/1.1730573
Abstract
Further expressions are developed which relate the parameters of the asymmetric rotator to experimental data through moments of the energy levels. The expressions developed here apply to an asymmetric rotator system described by a Hamiltonian which includes terms allowing for first‐order centrifugal stretching effects. A criterion for the applicability of the first‐order theory is given.Keywords
This publication has 10 references indexed in Scilit:
- Computation of Rigid Asymmetric Rotator Constants from Energy Moments. IIThe Journal of Chemical Physics, 1959
- Computation of Rigid Asymmetric Rotator Constants from Energy MomentsThe Journal of Chemical Physics, 1957
- Nuclear Magnetic Dipole and Electric Quadrupole Energy RelationsPhysical Review B, 1955
- Approximate Treatment of the Effect of Centrifugal Distortion on the Rotational Energy Levels of Asymmetric-Rotor MoleculesThe Journal of Chemical Physics, 1952
- Absorption spectrum of water vapor between 4.5 and 13 micronsJournal of Research of the National Bureau of Standards, 1952
- The Near Infra-Red Spectrum of Water Vapor. Part I. The Perpendicular BandsandPhysical Review B, 1941
- The Vibration-Rotation Energies of the Nonlinear TriatomicType of MoleculePhysical Review B, 1939
- Elements of the Factored Secular Equation for the Semi-Rigid Water Type Rotator, With Application to the Hydrogen Sulfide Band at 10,100AThe Journal of Chemical Physics, 1937
- The Effect of Rotational Distortion on the Thermodynamic Properties of Water and Other Polyatomic MoleculesThe Journal of Chemical Physics, 1936
- Zur Frage der Quantelung des asymmetrischen KreiselsThe European Physical Journal A, 1929