Reaction of pentafluoroethyl radicals with hydrogen cyanide

1 February 1983

journal article
research article
Published by Wiley in International Journal of Chemical Kinetics

Vol. 15 (2) , 187-196
https://doi.org/10.1002/kin.550150208

Abstract

The reaction of C₂F₅ radicals with HCN has been studied over the range of 533–673 K using the pyrolysis of pentafluoroethyl iodide as the free‐radical source. Arrhenius parameters for the reaction equation image relative to C₄F₁₀ recombination are given by where θ = 2.303RT kJ/mol and k_H/k is in cm^3/2/mol^1/2·s^1/2.

Keywords

This publication has 20 references indexed in Scilit:

Hydrogen abstraction by perfluoroethyl radicals from methylfluorosilanes
Canadian Journal of Chemistry, 1976
The reaction of C₂F₅ radicals with H₂S
International Journal of Chemical Kinetics, 1972
Reactions of perfluoroethyl radicals with ethane, n-butane and isobutane
Transactions of the Faraday Society, 1971
Reaction of hydrogen atoms with iodine cyanide
The Journal of Physical Chemistry, 1970
Reactions of CF3 (Trifluoromethyl) Radicals with Methylfluorosilanes
The Journal of Physical Chemistry, 1970
Reaction of oxygen atoms with iodine cyanide
The Journal of Physical Chemistry, 1968
Reactions of radicals containing fluorine. Part 1.—Hydrogen and deuterium atom abstraction from trideuteromethanol by trifluoromethyl radicals
Transactions of the Faraday Society, 1968
Reactions of trifluoromethyl radicals with organic halides. Part 5.—Fluoromethanes and fluoroethanes
Transactions of the Faraday Society, 1967
Reactions of trifluoromethyl radicals with bromine, chlorine and hydrogen chloride
Transactions of the Faraday Society, 1966
The recombination of atoms V. Iodine atom recombination in nitric oxide
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1962