Potassium Fluoride on Alumina: One-Pot Synthesis of Allyl Dithioesters by Tandem Condensation- Alkylation-Sigmatropic Rearrangement
- 1 August 1995
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 25 (15) , 2305-2310
- https://doi.org/10.1080/00397919508011787
Abstract
Methylene ketones adsorbed on KF-alumina at room temperature react quickly with carbon disulfide and two equivalents of allyl chloride. The products undergo sigmatropic rearrangement, to give the corresponding allyl ketodithioesters.Keywords
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