Deuterium isotope effects on one‐bond carbon, hydrogen coupling constants
- 1 July 1982
- journal article
- review article
- Published by Wiley in Magnetic Resonance in Chemistry
- Vol. 19 (3) , 169-172
- https://doi.org/10.1002/mrc.1270190313
Abstract
Small, negative deuterium isotope effects on 1J(CH) have been found for a variety of simple organic molecules. These new experimental data support theoretical calculations and suggestions based on previous imprecise experimental measurements. The deuterium isotope effects upon the 13C chemical shifts were also measured with high precision.Keywords
This publication has 26 references indexed in Scilit:
- CH, CD, CC and HH coupling constants in isotopically enriched cyclobuteneMagnetic Resonance in Chemistry, 1981
- Deuterium isotope effect on 1J(15N,13C) in hydrogen cyanideJournal of Magnetic Resonance (1969), 1980
- Magnitudes of 18O isotope shifts in 13C nuclear magnetic resonance spectra of ketones and alcoholsCanadian Journal of Chemistry, 1980
- Tritium nuclear magnetic resonance spectroscopy. Part 11. Further consideration of referencing, isotope effects and coupling constants: Preparation of [3H]tetramethylsilaneMagnetic Resonance in Chemistry, 1979
- Gas phase 13C chemical shifts and coupling constants in the deuteromethanesThe Journal of Chemical Physics, 1978
- Isotope effect on the coupling constant1J(13C–H)Journal of the Chemical Society, Chemical Communications, 1975
- The effect of isotopic substitution on spin-spin coupling constantsJournal of Magnetic Resonance (1969), 1973
- Deuterium Isotope Effect in Proton—13C Coupling ConstantsThe Journal of Chemical Physics, 1965
- Nuclear Magnetic Resonance Spectra of Silicon Hydrides and Derivatives. I. Coupling Constants Involving HydrogenThe Journal of Chemical Physics, 1962
- Electron Coupling of Nuclear Spins. V. Vibrational Effects in CHX GroupsThe Journal of Chemical Physics, 1962