An unusually strict product partition of an excited diazirine–carbene system
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1597-1599
- https://doi.org/10.1039/c39930001597
Abstract
Photolysis of 3-tert-butyl-3-chlorodiazirine produces 2-chloro-3-methyl-but-2-ene and 2,2-dimethyl-1-chlorocyclopropane; the former stems from 1,2-methyl migration and nitrogen loss in the excited state diazirine, whilst the latter is a product of 1,3-CH insertion in the tert-butylchlorocarbene derived from the diazirine.Keywords
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