Vibrational spectroscopy and intramolecular relaxation of benzene
- 15 November 1993
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 99 (10) , 7337-7349
- https://doi.org/10.1063/1.465715
Abstract
By making use of Lie algebraic methods, we construct the complete vibrational spectrum of benzene. We use this construction to study the process of intramolecular vibrational energy relaxation in the first and second overtone of the CH stretching mode.Keywords
This publication has 26 references indexed in Scilit:
- Quantum dynamics of overtone relaxation in benzene. I. 5 and 9 mode models for relaxation from CH(v=3)The Journal of Chemical Physics, 1992
- Comment on ‘‘Model ofncoupled anharmonic oscillators and applications to octahedral molecules’’Physical Review Letters, 1992
- Model ofncoupled anharmonic oscillators and applications to octahedral moleculesPhysical Review Letters, 1991
- The 3←0 CH stretch overtone of benzene: An optothermal studyThe Journal of Chemical Physics, 1991
- Infrared–ultraviolet double resonance studies of benzene molecules in a supersonic beamThe Journal of Chemical Physics, 1988
- Ionization-detected Raman studies of the 1600 cm−1 Fermi dyad of benzeneThe Journal of Chemical Physics, 1985
- The ν13 fundamental band of benzeneCanadian Journal of Physics, 1983
- The totally symmetric rotation‐vibrational Raman bands of benzeneJournal of Raman Spectroscopy, 1979
- High resolution rotation–vibration Raman spectra of benzene. II. The doubly degenerate bands of C6H6Canadian Journal of Physics, 1978
- Centre-of-mass effects in the nuclear shell-modelProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1955