Abstract
The usual method of determining diphosphothiamine (DPT) by its cocarboxylase activity proved unreliable when applied to blood extract because of a marked upward drift of the results during the period of measurement. This phenomenon, which was associated with excessively high recovery values, was tentatively attributed to a synthesis of DPT since the presence of 1 × 10−3 molar iodoacetate abolished the increase in carboxylase activity. Judging from recovery experiments, the addition of iodoacetate to the reactants permitted a more reliable estimation of the DPT content of blood extract.

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